Reinvestigation of the UV-VIS absorption spectra of the interhalogens, Ibr and Icl

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Reinvestigation of the UV-VIS absorption spectra of the interhalogens, Ibr and Icl

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dc.contributor Dolson, David A.
dc.contributor.author Stuck, Rachael
dc.coverage.temporal 2010 en_US
dc.date.accessioned 2011-06-13T19:21:25Z
dc.date.available 2011-06-13T19:21:25Z
dc.date.created 2010-04
dc.date.issued 2010-04
dc.identifier.other celebration_abstract10_stuck_r
dc.identifier.uri http://hdl.handle.net/2374.WSU/4697
dc.description.abstract

Absorption coefficients of ICI and IBr are of interest, in part because they are photolyzed to produce spin-orbit excited (2PX) CI* and Br* atoms in energy transfer studies. Notable differences currently exist for the vapor phase ICI absorption coefficients previously reported in scientific literature, and possibly correspond to sample purity. Additionally, only a single gas phase investigation of IBr absorption coefficients has been published. In the present work, great care was used in the preparation of ICI and IBr from stoichiometric amounts of the elemental halogens. Extinction coefficients for halogen (C12 and Br2) and interhalogen (lCI and IBr) vapors were determined in the 200 nm - 600 nm spectral range using a diode array spectrophotometer. Results for the elemental halogens are in excellent agreement with current recommendations. Results for the interhalogens will be compared to currently recommended values.

This presentation occurred at the Wright State University Campus-Wide Celebration of Research, Scholarship and Creative Activities on April 16, 2010

dc.language.iso en_US en_US
dc.publisher Wright State University en_US
dc.relation.ispartof Celebration of Research, Scholarship, and Creative Activities en_US
dc.rights.uri http://www.wright.edu/web/copyright.html
dc.subject Stuck, Rachael en_US
dc.subject Dolson, David A. en_US
dc.subject Wright State University. College of Science and Mathematics. Department of Chemistry en_US
dc.title Reinvestigation of the UV-VIS absorption spectra of the interhalogens, Ibr and Icl en_US
dc.type Presentation en_US
dc.permissions World
dc.publisher.digital Digital Services Department, Wright State University Libraries en_US
dc.date.digitized 2010-04
dc.publisher.OLinstitution Wright State University

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